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This binding of the side-chain polar substituents is, of course, supplementary to that of the amino and carboxylic acid groups which are assumed to provide a constant binding energy through relatively strong H-bonds to cellulose. The correlation indicates that binding of the polar side chains is controlled by H-bonds to cellulose hydroxyl groups in opposition to the repulsion of the predominantly hydrocarbyl structures. One possibility for the difference in binding mechanism may be attributed to the additional strength of the neutral carboxylic acid bond to cellulose.

H. J. Chem. Soc, Faraday Trans. 11981, 77, 1027-1038. 27. Rochester, C. -A. J. Chem. Soc, Faraday Trans. 11978, 74, 1125-1136. 28. Acosta Saracual, A. ; Rochester, C. H. J. Chem. Soc, Faraday Trans. 11982, 78, 2787-2791. 29. Pohle, W. / Chem. Soc, Faraday Trans. 11982, 78, 2101-2109. 30. Rochester, C. -A. J. Chem. Soc, Faraday Trans. 11978, 74, 1137-1145. 31. Snyder, L. R. J. Phys. Chem. 1963, 67, 240-248. 32. Snyder, L. R. J. Phys. Chem. 1963, 67, 234-240. 33. Snyder, L. R. / Phys. Chem. 1963, 67, 2344-2353.

From K values at various temperatures, the corresponding standard enthalpy changes are obtained. In all cases, the determination of K requires the simultaneous determination of the ratio of the partial pressures of the ions, p{D-)/p(A-) as a function of the reaction time. The pressures of the neutral reagents must be known; they can be determined by means of standard methods. (A-) are given by the ratios of ion intensities. ^"^ Comparison of the results obtained by these techniques has generally shown a quite satisfactory agreement.

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A Personification of Demos on a New Attic Document Relief by Kevin Glowacki


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